Chalkline's listing describes question-led tutoring from photographed problems and worked analogies. It states that full worked solutions in the app are available through a parent or teacher unlock.
Photomath's official site describes scanning math problems and exploring step-by-step explanations across supported topics.
Choose based on the learning interaction, then check whether you can solve a similar problem without the tool. An explanation is useful when it helps you learn a method rather than simply produce an answer.
Comparison based on current official descriptions, not hands-on testing of the competing product. Prices, subscription eligibility and feature availability can change.